Examination of mercaptobenzyl sulfonates as catalysts for native chemical ligation: application to the assembly of a glycosylated Glucagon-Like Peptide 1 (GLP-1) analogue.

نویسندگان

  • Ben Cowper
  • Tsz Mei Sze
  • Bhavesh Premdjee
  • Aileen F Bongat White
  • Andrew Hacking
  • Derek Macmillan
چکیده

3/4-Mercaptobenzyl sulfonates were investigated as aryl thiol catalysts for native chemical ligation (NCL). Whilst catalysing NCL processes at a similar rate to 4-mercaptophenyl acetic acid (MPAA), the increased polarity and solubility of 3-mercaptobenzyl sulfonate in particular may favour its selection as NCL catalyst in many instances.

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عنوان ژورنال:
  • Chemical communications

دوره 51 15  شماره 

صفحات  -

تاریخ انتشار 2015